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The material selection platform
Adhesives Ingredients
The material selection platform
Adhesives Ingredients

High Peel Strength, UV Curable Pressure Sensitive Adhesive

Adhesives Formulation

Applicable Type
Applicable Base Polymer
Applicable Industrial Sectors

Applicable Base Polymer Properties

Ultraviolet light (UV) curing PSA adhesives are creating significant interest for flexible packaging and tapes and labels. Acrylate / methacrylate monomers and oligomers as well as photoinitiators are essential components of UV adhesives. Aliphatic urethane acrylates are commonly used in laminations since they have good adhesion to most films and are non-yellowing. These adhesives are also characterized by a relatively low application viscosity.

Typical Formulation Ingredients

Ingredient
Parts by weight
Monofunctional aliphatic urethane acrylate oligomer (Genomer 4188/EHA, Rahn Energy Company) 
xx 
Tackifier, modified polyester resin (Co-Resin 02-819/M22, Rahn Energy Company) 
xx 
Diluent, isodecyl acrylate monomer (Miramer M130, Rahn Energy Company) 
xx 
Difunctional amine acrylate (Genocure 5275, Rahn Energy Company) 
x 
Photoinitiator (Genocure LTM, Rahn Energy Company) 
x 
(Source: Formulation Goals of Energy Curable Pressure Sensitive Adhesives, Rahn USA Corporation, 2006.) 
 

Typical Properties

Properties
Viscosity, cps 
xxxxx 
Loop tack, lb / in2 
xxxx 
Peel strength, lb / in 
xxxx 
Static shear strength @ 23°C, Hr 
xxxxxxxxxx 
Static shear strength @ 80°C, Hr 
xxxx 

Processing

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Resulting Properties

To obtain higher peel properties, the Genomer 4188/EHA content is maximized for its elastic characteristics. This enables a large extension of the adhesive during removal which provides strong adhesion in a PSA. Inert Co-Resin 02-819/M22 is incorporated as the tackifying resin which exhibits a relatively high Tg, +12ºC. In addition, the difunctional Genomer 5275 is incorporated to add a degree of crosslinking. The combination of increased crosslinking, Tg, and elasticity of the adhesive brings about the improvement in peel performance.

Tips and Tricks

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