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The material selection platform
Adhesives Ingredients
The material selection platform
Adhesives Ingredients

Polybutadiene Polyol Based Moisture Reactive Hot Melt Adhesive by Sartomer

Adhesives Formulation | Supplied by Sartomer (Arkema Group)

Applicable Type
Applicable Base Polymer
Applicable Industrial Sectors

Applicable Base Polymer Properties

Poly bd® Resins are hydroxyl-terminated polybutadiene homopolymers. They are low molecular weight reactive liquids that offer broad formulating opportunities to the adhesives manufacturer. They are extensively and successfully used as adhesives and sealants, and they have an excellent record of durability.

Typical Formulation Ingredients

Phase
Ingredient
Parts by weight
Polybutadiene resin (Poly BD® R45HTLO or Poly BD® LF-3, Sartomer) 
xx 
Terpolymer, EVA-HEA (OREVAC® 9402, Atofina) 
xx 
Tackifier (Kristalea F-85 from Hercules or Cray Valley) 
xxx 
[ISONATE™ 125 M, Dow Chemical/OH]1 
xxx 
[ISONATE™ 125 M, Dow Chemical/OH]2 
x 
Dodecanol / whole formulation 
xxxxxxx 
Synthesis protocols 
xxxxxxxx 

Typical Properties

Properties
Relativity low melt viscosity compared with a non-reactive adhesive 
 
Application temperature is a low 130°C 
 
Good resistance to peel on cotton 
 
Good SAFT on Kraft paper 
 

Processing

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Resulting Properties

A moisture-cure hot melt formulation based on EVA- HEA (hydroxyl containing EVA resin) and Poly bd® is described in the formulation above. Using polybutadiene polyol will provide much better hydrolytic stability than other conventional polyols (e.g., polyester or polyether).

Often additives are not required to provide flexibility or toughness. Polyurethanes have the capability of providing these properties through manipulation of the resulting molecule by proper choice of isocyanate and polyol. However, additives are used mainly to stabilize the adhesive relative to moisture, oxidation, UV, etc.

Tips and Tricks

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