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Adhesives Ingredients
The material selection platform
Adhesives Ingredients

Moisture Curable Polyurethane Hot Melt Adhesive

Adhesives Formulation

Applicable Base Polymer
Applicable Industrial Sectors

Applicable Base Polymer Properties

Reactive polyurethane hot melt (HMPUR) adhesives are highly viscous or solid prepolymers with a low melting point. Reacting solid polyether or polyester polyol mixtures with an excess of diisocyanate produces the solid polyurethane prepolymer. The reaction of the isocyanate group (NCO) with an alcohol group (OH) on the polyol produces the urethane group. The resulting product has a low number of free isocyanate groups depending on the final molecular weight and melt viscosity.

Typical Formulation Ingredients

Ingredient
Parts by weight
Crystalline polyester polyol (high crystallinity) 
xx 
Amorphous polyester polyol (solid) 
xx 
Thermoplastic polyurethane (Pearlbond TPU, Lubrizol) 
xxxx 
Methylene diphenyl diisocyanate (MDI) 
xxxx 
Amorphous polyester polyol (liquid) 
xxxx 
(Source: Lubrizol) 
 

Typical Properties

Properties
• OH / NCO ratio = 1:1.95 
 
• Low application temperature 
 
• Immediate green strength and rapid increase of the cohesive strength (crosslinking) 
 
• The cross-linked adhesive has an excellent resistance to heat and ambient conditions 
 
• Good adhesion to a variety of substrates 
 

Processing

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Resulting Properties

By being capable of curing to a thermosetting material, reactive hot melt adhesives eliminate or greatly reduce many of the performance problems associated with conventional hot melt adhesives. In addition, reactive hot melt adhesives have the ability to bond to many different substrates and, generally, have longer service life times. Before the HMPUR adhesive reacts with ambient moisture, it must exhibit the properties of a conventional hot melt system. Typical application temperatures for HMPUR adhesives are in the range of 85°-140°C with melt viscosities from 2,000 to 80,000 cps. Application temperature and viscosity can be engineered by the balance of polyester and polyether components and the degree of amorphous structure in the polymer.

Tips and Tricks

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