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The material selection platform
Adhesives Ingredients
The material selection platform
Adhesives Ingredients

Repulpable Polyester Hot Melt Adhesive for Paper Packaging

Adhesives Formulation

Applicable Type
Applicable Base Polymer
Applicable Industrial Sectors

Applicable Base Polymer Properties

The water-dispersible polyesters are branched, amorphous materials comprised of difunctional acids and various glycols. Their water-dispersibility is due to the presence of pendent sodiosulfo groups randomly distributed along the polymer backbone. The unique properties of the new polyester are derived from a branched architecture and a specific combination of monomers resulting in a low Tg and enhanced compatibility with other resins. The low Tg provides, in part, the means by which water-dispersibility is readily obtained at or below room temperature. The branched structure of the polyester results in low melt viscosity profiles that are required for hot-melt adhesive formulations.

Typical Formulation Ingredients

Ingredient
Parts by weight
Polyester resin (WDP-4.5, Eastman Chemical) 
xx 
Aromatic tackifier resin (Nevex 100, Neville Chemical Co.) 
xx 
Solid plasticizer (Benzoflex 352, Eastman Chemical) 
xxx 
Primary antioxidant 
xxxx 
Secondary antioxidant 
xxxx 
(Source: Miller, R.A. and Althen, G., “Optimization of Hot Melt Adhesives Using Water Dispersible Polyesters”, Proceedings of the TAPPI Hot Melt Adhesive Seminar 1996.) 
 

Typical Properties

Properties
Viscosity @ 177°C per ASTM D3236, cps 
xxxx 
Set time, sec 
xxx 
Peel adhesion failure temperature (PAFT), °C 
xx 

Processing

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Resulting Properties

Using the key criteria of low viscosity and fast set time, a starting point formulation using the WDP-4.5 as the base polymer was identified.. The water dispersible polyester based formulation compared favorably to the performance characteristics of conventional adhesives for elevated temperature performance and setting characteristics.

Tips and Tricks

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