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New Huntsman Jeffamine® Amines Enable Modification of Polyurea Curing Speeds

Published on 2007-05-14. Author : SpecialChem

Formulators wanting to modify the cure speed of polyurea and polyurethane-based systems to give customers more open time and control for specialist coating, elastomer, adhesive and sealant applications, have a brand new technology at their disposal, thanks to Huntsman Performance Products – one of the world’s largest manufacturers of amine products.

JEFFAMINE® SD 231, SD-401 and SD-2001 amines are high content, secondary aliphatic, liquid polyetheramines. The secondary amine functional groups provide a much slower reaction compared to primary amines and are capable of significantly slowing down the cure speed of polyurea/polyurethane elastomeric coating systems. Designed to be used in conjunction with aromatic or aliphatic chain extenders, or to partially replace existing primary polyether amines, they can improve the flexibility and colour of aromatic formulations, while reducing the overall cost of development.

As low viscosity liquids, these new secondary aliphatic diamines allow the efficient formation of much lower viscosity isocyanate prepolymers, with properties equivalent to primary polyetheramines or polyols used. The products are stable and there is no off-gassing of reversible blocking agents. They can also expand the formulation capabilities of aspartic esters and aromatic formulations at a lower cost, with equivalent performance properties.

Secondary aliphatic polyetheramines also allow the formation of high hardness aromatic and aliphatic systems, while maintaining flexibility and good cure speeds at a reasonable cost. When using these amines as reactants, their amine groups – which are secondary in nature – prevent more than one reaction at each amine site.

Commenting on the launch, Martin Michiels, Commercial Director for Huntsman Performance Products said: “Secondary amines are a real enabling technology for formulators creating aliphatic polyurea coatings. Their use, in combination with Huntsman’s JEFFLINK® aliphatic amine chain extender, allows the production of coatings that offer excellent physical properties, reasonable cure times and have the added benefit of colour and UV stability. The introduction of these latest JEFFAMINE® products opens up a wealth of new and exciting coating applications for polyurea which were once the sole domain of aliphatic polyurethanes.”

Continuing he said, “Using our unique technological capabilities, experts at Huntsman can identify and formulate the specific chemical structure needed to deliver the performance properties required by our customers. Approaching our science with creativity, and by accessing a broad spectrum of solutions, Huntsman can tailor make solutions to fulfill all our customers’ requirements.”

The JEFFAMINE® polyetheramines range is proprietary to Huntsman. They bear EINECS (polymers) and TSCA registration. Development quantity samples are available upon request:

About Huntsman

Huntsman is a global manufacturer and marketer of differentiated chemicals. Its operating companies manufacture products for a variety of global industries, including chemicals, plastics, automotive, aviation, textiles, footwear, paints and coatings, construction, technology, agriculture, health care, detergent, personal care, furniture, appliances and packaging. Originally known for pioneering innovations in packaging and, later, for rapid and integrated growth in petrochemicals, Huntsman today has 14,000 employees and over 75 operations in 24 countries. The Company had 2006 revenues from all operations of over $13 billion.

JEFFAMINE® and JEFFLINK® are registered trademarks of Huntsman Corporation or an affiliate thereof in one of more, but not all countries.

Statements in this release that are not historical are forward-looking statements. These statements are based on management’s current beliefs and expectations. The forward-looking statements in this release are subject to uncertainty and changes in circumstances and involve risks and uncertainties that may affect the company’s operations, markets, products, services, prices and other factors as discussed in the Huntsman companies’ filings with the Securities and Exchange Commission. Significant risks and uncertainties may relate to, but are not limited to, financial, economic, competitive, environmental, political, legal, regulatory and technological factors. In addition, completion of transactions of the type described in this release is subject to a number of uncertainties and to negotiation and execution of definitive agreements among the parties and closing will be subject to approvals and other customary conditions. Accordingly, there can be no assurance that the transactions will be completed or that the company’s expectations will be realized. The company assumes no obligation to provide revisions to any forward-looking statements should circumstances change, except as otherwise required by securities and other applicable laws. For additional information, please see our current report on form 8-K filed on the date hereof concerning the same subject matter.

Source: Huntsman


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