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Using Hyperbranched Polymers in Epoxy Thermosets

SpecialChem / Andy Extance – Apr 4, 2012

While thermoset epoxy adhesives are commercially successful their shrinkage on curing, toughness and reworkability could be improved. Hyperbranched polymers, large molecules with many functional endings to branches extending from a central chemical group, are helping meet these needs.

Thermoset epoxy adhesives are such a widely- and successfully-used set of products that you might question whether the technology needs further improvement. For example, in the production of high-performance composites, thermosetting epoxy adhesives offer an excellent cost:performance ratio. Nevertheless, ever more demanding requirements do necessitate improvements in areas such as the degree to which the adhesive shrinks upon curing, toughness and reworkability.

One relatively new class of additives and modifiers that looks to be capable of meeting these needs is the hyperbranched polymers (HBPs), large molecules with many functional endings to branches extending from a central chemical group.

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