TAGS: Sustainability / Natural Adhesives Sealants
A team of UK scientists has got a step closer to making several different types of plastic much easier to recycle, using a method that could be applied to a whole range of difficult-to-recycle polymers, including rubbers, gels and adhesives.
Thermoplastics and thermosets are two types of plastics that both consist of long chains of molecules called polymers but behave differently when heated.
Introduce Degradable Bonds into Thermoset Polymers
Thermoplastics can be heated to high temperatures, poured into a mold then cooled to make the desired shape. They can subsequently be melted and reformed into other shapes when they are recycled, however they can break when stretched or stressed.
In contrast, the polymer chains in thermoset plastics are crosslinked to form a network which makes them incredibly strong and flexible. They are often used in composite materials, paints, coatings, rubbers and gels. Unfortunately, however, the crosslinks mean that the materials burn rather than melt when heated, making them much harder to break down and recycle.
Enhance Recyclability of Adhesive Polymers
Researchers at the University of Bath and the University of Surrey have developed a way of introducing degradable bonds into thermoset polymers to make them more easily recyclable.
They made a series of polymer gels with breakable bonds incorporated into different parts of the structure and tested whether the properties changed after the gel was degraded and reformed.
They found that whilst all the gels could be degraded to some extent, gels with breakable bonds in the polymer chains retained their properties much better when reformed, compared with the polymers that were broken down via the cross-linked bonds.
The researchers hope this model system can be applied to other types of polymers, including adhesives, sealants and elastomers.
“
Thermosets are used widely in the commercial sector, in materials like resins and adhesives. Being able to make bonds reversible in these materials will increase their applications as well as make them more recyclable,” said Dr Maciek Kopeć, from the University of Bath’s Department of Chemistry.
The researchers aim to create a general road map of the best locations for these breakable bonds, to understand better why some bonds break more easily than others, and plan to optimize the system using other commercially used polymers.
The researchers are also looking at other applications of the work, including using crosslinked polymers as vehicles for controlled drug delivery systems.
The work was funded by the Engineering and Physical Sciences Research Council (EPSRC).
Source: University of Bath